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La Sardegna e l’abbazia di Saint-Victor di Marsiglia - Le fonti negli Archives Départementales des Bouches-du-Rhône

Synthesis, characterization and applications of complexes with transition metal ions in d6, d8 and d10 configuration, with nitrogen heterocyclic ligands containing pyridinic nuclei.

This PhD project in Chemical Sciences and Technologies focused on the synthesis, reactivity and applications of various nitrogen-containing heterocyclic ligands containing pyridine nuclei and their derivatives with transition metal ions, mainly in d8 configuration, including Pd(II), Pt(II) and Au(III). The ligands studied belong to the following classes: i. 2-substituted pyridines and 6-substituted 2,2'-bipyridines ii. 3-substituted 1-(2-pyridyl)imidazo[1,5-a]pyridines iii. 1,3-bis-(2-pyr...

Biospeciation, Interaction with Biomolecules and Mechanism of Action of Potential Cu and V Drugs

This doctoral project focused on copper(II) and vanadium(IV) complexes as prospective metallodrugs, investigating their coordination chemistry, speciation, and reactivity in biologically relevant media. A wide set of ligands, including phenanthroline derivatives, pyridinones, thiosemicarbazones, hydrazones, and 8-hydroxyquinoline, was employed to explore the structural diversity of these systems. The interactions of these metal complexes with proteins such as myoglobin, ubiquitin, lysozyme, c...

Design and synthesis of new materials for the protection, restoration, and conservation of carbonate stone artifacts of interest in the field of Cultural Heritage.

The conservation of carbonate stone materials, commonly found in historical architecture and sculpture, poses significant challenges due to their susceptibility to weathering and chemical degradation. This PhD research focuses on developing innovative inorganic treatments to improve the durability of calcareous substrates by forming insoluble and chemically compatible protective phases. Among the most studied consolidants, calcium oxalates, oxamates, and phosphates exhibit promising propertie...

DESIGN OF NOVEL ORGANIC MOLECULES AND METAL COMPLEXES WITH BIOLOGICAL PROPERTIES

This thesis summarizes the research activity I carried out during the three years of my PhD, focusing on the design and study of bioactive molecules and Copper (II) complexes, as well as the development of innovative analytical methods applied to different systems. The core of this work is focused on synthesis and characterization of a series of copper (II) complexes bearing different classes of organic ligands, with the aim of discovering novel potential anticancer molecules. The biological ...

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