Materiali molecolari basati su complessi inorganici

Synthesis and characterization of molecular materials based on inorganic complexes. Recent news and perspectives about molecular materials. Syntheses of croconate (croc) and dithiocroconate (dtcr) ligands. New complexes based on croconate and dithiocroconate ligands, spectroscopic and structural properties of (TBA)2[Cu(dtcr)2], (TBA)[Au(dtcr)2], (TBA)3[Ga(croc)3]. New charge transfer salts based on dithiocroconate ligand, structural properties and electrical conductivity behavior of ET2[Ni(dtcr)2], TTF2[Ni(dtcr)2] e ET[Au(dtcr)2], initial spectroscopic characterization of ET/[Cu(dtcr)2] e TTF/[Cu(dtcr)2]. New complexes of Cr(III) with croconate ligand, spectroscopic and structural properties of [Cr(µ-C5O5)(µ-OH)(OH2)2]2[K5(C5O5)2.5]•7H2O e [Cr(µ-C5O5)(µ-OH)(OH2)2]2•6H2O, preliminary studies of magnetic properties and DFT calculations to clarify the bridge structure of the dimer [Cr(µ-C5O5)(µ-OH)(OH2)2]2•6H2O. Future perspectives on the use of these new complexes in the field of molecular materials.