Regioselective synthesis of 2,4,5- or 3,4,5-trisubstituted 2,3-dihydrofurans has been realized by using donor-acceptor cyclopropanes or by a Corey ylide reaction with alpha-sulfenyl-, alpha-sulfinyl-, or alpha-sulfonylen ones. The method allowed a straightforward synthesis of the natural product calyxolane B.
Regioselective Synthesis of Trisubstituted 2,3-Dihydrofurans from Donor−Acceptor Cyclopropanes or from Reaction of the Corey Ylide with α-Sulfenyl-, α-Sulfinyl-, or α-Sulfonylenones
BERNARD, ANGELA MARIA;FRONGIA, ANGELO;SECCI, FRANCESCO;SPIGA, MARCO
2005-01-01
Abstract
Regioselective synthesis of 2,4,5- or 3,4,5-trisubstituted 2,3-dihydrofurans has been realized by using donor-acceptor cyclopropanes or by a Corey ylide reaction with alpha-sulfenyl-, alpha-sulfinyl-, or alpha-sulfonylen ones. The method allowed a straightforward synthesis of the natural product calyxolane B.
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