X-ray diffraction, FT-Raman spectroscopy and MP2/DFT theoretical calculations have been used to elucidate the nature of the products isolated from the reactions between three pyridyl donors, N-ethyl-N′-3-pyridyl-imidazolidine-4,5-dione-2-thione (1), N,N′-bis(3-pyridylmethyl)-imidazolidine-4,5-dione-2-thione (2), and tetra-2-pyridyl-pyrazine (3), and Br2, I2, IBr, and ICl. Both σ-type CT-adducts and polyhalide salts of the protonated donors have been characterised.
Titolo: | Reactions of pyridyl donors with halogens and interhalogens: an X-ray diffraction and FT-Raman investigation | |
Autori: | ||
Data di pubblicazione: | 2005 | |
Rivista: | ||
Handle: | http://hdl.handle.net/11584/12817 | |
Tipologia: | 1.1 Articolo in rivista |
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