A novelmetal-free oxidative crossesterification of alcohols has been achieved usingtrichloroisocyanuric acid as an oxidant. Thealco-hols were converted in situ into theircorrespondingacyl chlorides,which were then reacted with pri-mary and secondary aliphatic,benzylic and allylicalcohols and phenols.Awide variety of esters wasobtained in satisfactory yields
Metal-free oxidative cross esterification of alcohols via acyl chloride formation
GASPA, SILVIA;PORCHEDDU, ANDREA;
2016-01-01
Abstract
A novelmetal-free oxidative crossesterification of alcohols has been achieved usingtrichloroisocyanuric acid as an oxidant. Thealco-hols were converted in situ into theircorrespondingacyl chlorides,which were then reacted with pri-mary and secondary aliphatic,benzylic and allylicalcohols and phenols.Awide variety of esters wasobtained in satisfactory yields
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