The title compound, [Pd2(C11H14NO)2Cl2], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the molecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd2Cl2 ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intramolecular N!Pd coordination trans to a Pd—Cl bond. In the crystal structure, the dimeric structure is strengthened by intermolecular C—H Cl hydrogen bonds. C—H Cphenyl interactions link the dimers into a columnar supramolecular array along the a axis; the dimers are further connected by C— H Ph interactions into a three-dimensional supramolecular arrangement.
Di-m-chlorido-bis{[morpholino-methyl)phenyl-ĸ2C1,N]palladium(II)}
ISAIA, FRANCESCO;
2008-01-01
Abstract
The title compound, [Pd2(C11H14NO)2Cl2], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the molecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd2Cl2 ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intramolecular N!Pd coordination trans to a Pd—Cl bond. In the crystal structure, the dimeric structure is strengthened by intermolecular C—H Cl hydrogen bonds. C—H Cphenyl interactions link the dimers into a columnar supramolecular array along the a axis; the dimers are further connected by C— H Ph interactions into a three-dimensional supramolecular arrangement.
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