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EnglishIn the crystal structure of the title compound, [(C24H21NO2P2)2H]+.I3 - , the triiodide anion is linear, sitting across a centre of symmetry, with I—I distances of 2.9130 (6) A ˚ . The [H{(OPPh2)2NH}2]+ cation is formed by two symmetry-related molecules of tetraphenylimidodiphosphinic acid, (OPPh2)2NH, exbiting for the O—P—N—P—O skeleton an anti conformation [code (-,+)/(+,-)] with an angular P—N—P fragment. The charge is determined by a single proton shared by these two molecules, disordered across a centre of symmetry and forming an O—H...O hydrogen bond.
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| Titolo: | Hydrogen bis(tetraphenylimidodophosphonic acid) triiodide | |
| Autori: | ||
| Data di pubblicazione: | 2007 | |
| Rivista: | ||
| Abstract: | In the crystal structure of the title compound, [(C24H21NO2P2)2H]+.I3 - , the triiodide anion is linear, sitting across a centre of symmetry, with I—I distances of 2.9130 (6) A ˚ . The [H{(OPPh2)2NH}2]+ cation is formed by two symmetry-related molecules of tetraphenylimidodiphosphinic acid, (OPPh2)2NH, exbiting for the O—P—N—P—O skeleton an anti conformation [code (-,+)/(+,-)] with an angular P—N—P fragment. The charge is determined by a single proton shared by these two molecules, disordered across a centre of symmetry and forming an O—H...O hydrogen bond. | |
| Handle: | http://hdl.handle.net/11584/18509 | |
| Tipologia: | 1.1 Articolo in rivista |
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