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EnglishThe coordination chemistry of 2,8-dithia[9],(2,9)-1,10-phenanthrolinophane (L) towards transition and post-transition metal ions such as Cu(II), Cu(I), Cd(II), Co(II), Ni(II), Pb(II) and Zn(II) was studied at the polarized water/1,2-dichloroethane interface by cyclic voltammetry. The dependence of the half-wave transfer potential on the ligand and metal concentrations was used to formulate the stoichiometry, and to evaluate the association constants of the complexes formed between L and Pb(II).
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| Titolo: | Electrochemistry of 2,8-dithia[9],(2,9)-1,10-phenanthrolinophane (L) at the polarized water/1,2-dichloroethane interface: Evaluation of the complexation properties towards transition and post-transition metal ions |
| Autori: | |
| Data di pubblicazione: | 2006 |
| Rivista: | |
| Citazione: | Electrochemistry of 2,8-dithia[9],(2,9)-1,10-phenanthrolinophane (L) at the polarized water/1,2-dichloroethane interface: Evaluation of the complexation properties towards transition and post-transition metal ions / E.S. FERREIRA; A. GARAU; LIPPOLIS V; C.M. PEREIRA; F. SILVA. - 587(2006), pp. 155-160. |
| Abstract: | The coordination chemistry of 2,8-dithia[9],(2,9)-1,10-phenanthrolinophane (L) towards transition and post-transition metal ions such as Cu(II), Cu(I), Cd(II), Co(II), Ni(II), Pb(II) and Zn(II) was studied at the polarized water/1,2-dichloroethane interface by cyclic voltammetry. The dependence of the half-wave transfer potential on the ligand and metal concentrations was used to formulate the stoichiometry, and to evaluate the association constants of the complexes formed between L and Pb(II). |
| Handle: | http://hdl.handle.net/11584/18557 |
| Tipologia: | 1.1 Articolo in rivista |
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