The ancient pozzolanic mortars and concretes of Heliocaminus baths in Hadrian's Villa (Tivoli, Italy)

Aim of this work is physical and mineralogical-petrographic characterization of the mortars from the Baths with Heliocaminus, a special and unique architectural building in the complex of the Hadrian’s Villa in Tivoli. 30 samples were investigated for composition and physical properties (density, porosity, water absorption, mechanical strength, particle-size distribution of aggregate, etc.), representative of eight mortar groups: cubilia mortar, brick bedding mortars, floor-coating and wall-coating bedding mortars, floor (rudus) and wall conglomerates (trullisatio), vault concretes, lime plasters (arriccio). Physical parameters, together the microscopic analysis and binder/aggregate ratio determined in three ways using image analysis (on thin sections and on specimens) and weight-data from dissolution of binder, have shown interesting relationship between the physical-compositional characteristics and the function of mortars within the structure of the Heliocaminus baths. To identify the minerals and the reactant phases between binder and aggregate, as well as the hydraulic degree, selected samples were analysed with X-Ray powder diffraction (XRPD), thermogravimetry (TGA) and differential scanning calorimetry (DSC) techniques. The obtained results provide a close relation between pozzolanic characteristics and physical-mechanical properties of the mortars (i.e., punching strength index).