We investigated the flexibility of high-temperature thermal decomposition synthesis to design magnetic nanoparticles (NPs) with engineered properties. We prepared spinel iron oxide particles with the desired composition (Fe3O4 and CoFe2O4) and a well-controlled average size (5−8 nm) by tuning the synthesis procedure. The substitution of Fe by Co produces a dramatic increase of the magnetocrystalline anisotropy: for 5 nm particles, the anisotropy constant increased from ∼3.9×104 to ∼7.5×105 J/m3. The magnetocrystalline anisotropy has shown a major effect on the magnetic behavior of highly crystalline particles, except for the smallest iron oxide sample, where the surface anisotropy plays a dominant role. The presence of surfactant (oleic acid) on the NPs surface prevents direct exchange coupling among them, whereas the dipolar interaction was predominant, with an estimated temperature-equivalent energy in the range of 4−60 K.

Magnetic interactions versus magnetic anisotropy in spinel ferrite nanoparticles

Muscas G.;Cannas C.;Musinu A.;Mameli V.;
2019-01-01

Abstract

We investigated the flexibility of high-temperature thermal decomposition synthesis to design magnetic nanoparticles (NPs) with engineered properties. We prepared spinel iron oxide particles with the desired composition (Fe3O4 and CoFe2O4) and a well-controlled average size (5−8 nm) by tuning the synthesis procedure. The substitution of Fe by Co produces a dramatic increase of the magnetocrystalline anisotropy: for 5 nm particles, the anisotropy constant increased from ∼3.9×104 to ∼7.5×105 J/m3. The magnetocrystalline anisotropy has shown a major effect on the magnetic behavior of highly crystalline particles, except for the smallest iron oxide sample, where the surface anisotropy plays a dominant role. The presence of surfactant (oleic acid) on the NPs surface prevents direct exchange coupling among them, whereas the dipolar interaction was predominant, with an estimated temperature-equivalent energy in the range of 4−60 K.
2019
Cobalt ferrite; Magnetic anisotropy; Magnetic interactions; Magnetic nanoparticles; Magnetite
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11584/282827
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