The photoconducting properties of platinum diimine-dithiolate complex [Pt(bipy)(Naph-edt)] (1; bipy = 2,2’-bipyridine; Naph-edt2− = 2-naphthylethylene-1,2-dithiolate) were investigated. DFT calculations on a model assembly with four complex units suggest that the high external quantum efficency measured on a prototype photodetector correlates with the intermolecular character of electronic excitations in the visible region.
Platinum diimine-dithiolate complexes as a new class of photoconductive compounds for pristine photodetectors: case study on [Pt(bipy)(Naph-edt)]
M. Carla AragoniPrimo
;Massimiliano Arca
;Claudia Caltagirone;Vito Lippolis;Enrico Podda;Anna Pintus
2021-01-01
Abstract
The photoconducting properties of platinum diimine-dithiolate complex [Pt(bipy)(Naph-edt)] (1; bipy = 2,2’-bipyridine; Naph-edt2− = 2-naphthylethylene-1,2-dithiolate) were investigated. DFT calculations on a model assembly with four complex units suggest that the high external quantum efficency measured on a prototype photodetector correlates with the intermolecular character of electronic excitations in the visible region.
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