All at once: The simultaneous synthesis and enantioselective functionalization of an indole core is achieved with the assistance of chiral cationic AuI complexes. A range of vinyloxazino-[4,3-a]indoles is obtained by a cascade process in a highly enantioselective manner (see scheme; L=chiral diphosphine). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Merging synthesis and enantioselective functionalization of indoles by a gold-catalyzed asymmetric cascade reaction
Mocci R.;
2013-01-01
Abstract
All at once: The simultaneous synthesis and enantioselective functionalization of an indole core is achieved with the assistance of chiral cationic AuI complexes. A range of vinyloxazino-[4,3-a]indoles is obtained by a cascade process in a highly enantioselective manner (see scheme; L=chiral diphosphine). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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