All at once: The simultaneous synthesis and enantioselective functionalization of an indole core is achieved with the assistance of chiral cationic AuI complexes. A range of vinyloxazino-[4,3-a]indoles is obtained by a cascade process in a highly enantioselective manner (see scheme; L=chiral diphosphine). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Merging synthesis and enantioselective functionalization of indoles by a gold-catalyzed asymmetric cascade reaction

Mocci R.;
2013-01-01

Abstract

All at once: The simultaneous synthesis and enantioselective functionalization of an indole core is achieved with the assistance of chiral cationic AuI complexes. A range of vinyloxazino-[4,3-a]indoles is obtained by a cascade process in a highly enantioselective manner (see scheme; L=chiral diphosphine). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
2013
allylic alkylation
asymmetric catalysis
cascade reaction
gold
indoles
Alkylation
Catalysis
Gold
Indoles
Oxazines
Stereoisomerism
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11584/349587
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