Mechanochemical activation of iron cyano complexes by ball milling results in the formation of HCN, which can be trapped and incorporated into alpha-aminonitriles. This prebiotic impact scenario can be extended by mechanochemically transforming the resulting alpha-aminonitriles into alpha-amino amides using a chemical route related to early Earth conditions.
Mechanochemical Activation of Iron Cyano Complexes: A Prebiotic Impact Scenario for the Synthesis of α-Amino Acid Derivatives
Mocci, Rita;
2018-01-01
Abstract
Mechanochemical activation of iron cyano complexes by ball milling results in the formation of HCN, which can be trapped and incorporated into alpha-aminonitriles. This prebiotic impact scenario can be extended by mechanochemically transforming the resulting alpha-aminonitriles into alpha-amino amides using a chemical route related to early Earth conditions.
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