The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.
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Titolo: | Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion |
Autori: | |
Data di pubblicazione: | 2012 |
Rivista: | |
Abstract: | The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes. |
Handle: | http://hdl.handle.net/11584/44955 |
Tipologia: | 1.1 Articolo in rivista |
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