The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.

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Titolo: Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion
Autori: 
ARAGONI, MARIA CARLA
ARCA, MASSIMILIANO
ISAIA, FRANCESCO
LIPPOLIS, VITO
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Data di pubblicazione: 2012
Rivista: 
DALTON TRANSACTIONS  
Abstract: The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.
Handle: http://hdl.handle.net/11584/44955
Tipologia:1.1 Articolo in rivista

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http://hdl.handle.net/11584/44955
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