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EnglishX-ray absorption spectroscopy (XAS) and high-resolution X-ray diffraction are combined to study the interplay between electronic and lattice structures in controlling the superconductivity in cuprates with a model charge-compensated CaxLa1- xBa1.75-xLa0.25+xCu3Oy (0≤x<0.5, y7.13) system. In spite of a large change in Tc, the doped holes, determined by the Cu L and O K XAS, hardly show any variation with the x. On the other hand, the CuO2 plaquette size shows a systematic change due to different size of substituted cations. The results provide a direct evidence for the chemical pressure being a key parameter for controlling the superconducting ground state of the cuprates
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| Titolo: | Experimental evidence of chemical-pressure-controlled superconductivity in cuprates |
| Autori: | |
| Data di pubblicazione: | 2009 |
| Rivista: | |
| Abstract: | X-ray absorption spectroscopy (XAS) and high-resolution X-ray diffraction are combined to study the interplay between electronic and lattice structures in controlling the superconductivity in cuprates with a model charge-compensated CaxLa1- xBa1.75-xLa0.25+xCu3Oy (0≤x<0.5, y7.13) system. In spite of a large change in Tc, the doped holes, determined by the Cu L and O K XAS, hardly show any variation with the x. On the other hand, the CuO2 plaquette size shows a systematic change due to different size of substituted cations. The results provide a direct evidence for the chemical pressure being a key parameter for controlling the superconducting ground state of the cuprates |
| Handle: | http://hdl.handle.net/11584/89394 |
| Tipologia: | 1.1 Articolo in rivista |
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http://hdl.handle.net/11584/89394
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