Graphene/ionic liquids nanocomposite gels were synthesized by an electrochemical etching approachand fully characterized under a morphological and structural point of view. For this purpose,several analytical techniques were applied, as HR-TEM/EDX (High Resolution-Transmission Elec-tron Microscopy/Energy Dispersive X-Ray Analysis); FE-SEM/EDX (Field Emission-Scanning ElectronMicroscopy/Energy Dispersive X-Ray Analysis); XPS (X-Ray Photoelectron Spectroscopy); FT-IR (FourierTransform-Infrared Spectroscopy) and electrochemical techniques. After the characterization study,nanocomposite-gel paste electrodes were assembled, exhibiting a selective and specific detectiontoward the caffeic acid oxidation. Better performances in terms of linear range of concentration (from0.025 to 2.00 M), reproducibility (intra-; 1.40% and inter-electrode reproducibility-3.20%), sensitivity(3389/A mM−1cm−2), fast response time (2 s) and detection limit (0.005 mM) were obtained, in compar-ison with other chemically modified electrodes, described in literature for the caffeic acid detection. Thisnanocoposite-gel could represent a new prototype of miniaturized nanostructured sensors useful for the“in situ” quantification of an important molecule, having pharmacological properties, anti-inflammatory,antibacterial, antiviral, immunomodulatory and antioxidant effects.
Graphene and Ionic Liquids new Gel paste electrodes for caffeic acid quantification
SABBATINI, LUIGIA;
2015-01-01
Abstract
Graphene/ionic liquids nanocomposite gels were synthesized by an electrochemical etching approachand fully characterized under a morphological and structural point of view. For this purpose,several analytical techniques were applied, as HR-TEM/EDX (High Resolution-Transmission Elec-tron Microscopy/Energy Dispersive X-Ray Analysis); FE-SEM/EDX (Field Emission-Scanning ElectronMicroscopy/Energy Dispersive X-Ray Analysis); XPS (X-Ray Photoelectron Spectroscopy); FT-IR (FourierTransform-Infrared Spectroscopy) and electrochemical techniques. After the characterization study,nanocomposite-gel paste electrodes were assembled, exhibiting a selective and specific detectiontoward the caffeic acid oxidation. Better performances in terms of linear range of concentration (from0.025 to 2.00 M), reproducibility (intra-; 1.40% and inter-electrode reproducibility-3.20%), sensitivity(3389/A mM−1cm−2), fast response time (2 s) and detection limit (0.005 mM) were obtained, in compar-ison with other chemically modified electrodes, described in literature for the caffeic acid detection. Thisnanocoposite-gel could represent a new prototype of miniaturized nanostructured sensors useful for the“in situ” quantification of an important molecule, having pharmacological properties, anti-inflammatory,antibacterial, antiviral, immunomodulatory and antioxidant effects.
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