alpha-Phenoxy- and phenylthio-ketones have been explored as donors and acceptors in organocatalytic aldol reactions. Our studies have revealed effective methodologies for accessing structurally varied and enantiomerically enriched secondary and tertiary phenylthio- and phenoxy-aldols, expanding the scope and potential synthetic utility of organocatalytic direct aldol reactions. (C) 2008 Elsevier Ltd. All rights reserved.
Synthesis of enantiomerically enriched secondary and tertiary phenylthio- and phenoxy-aldols
BERNARD, ANGELA MARIA;FRONGIA, ANGELO;SECCI, FRANCESCO;
2008-01-01
Abstract
alpha-Phenoxy- and phenylthio-ketones have been explored as donors and acceptors in organocatalytic aldol reactions. Our studies have revealed effective methodologies for accessing structurally varied and enantiomerically enriched secondary and tertiary phenylthio- and phenoxy-aldols, expanding the scope and potential synthetic utility of organocatalytic direct aldol reactions. (C) 2008 Elsevier Ltd. All rights reserved.
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