Organic-inorganic hybrid films containing layered organosilica, nanocrystals are obtained by an alcohol-free hydrolytic sol-gel process from a mono-functionalized organically modified alkoxide. Kinetically controlled self-organization is used to design the hybrid nanocomposite films. The layered nanocrystals are shown to be oriented within the films, which exhibited optical anisotropy (delta n > 10(-3)); the hybrid nanocomposite material is shown to be suitable for microfabrication by soft lithography. RI Takahashi, Masahide/C-3326-2009; Innocenzi, Plinio/D-5301-2009
Self-organized nanocrystalline organosilicates in organic-inorganic hybrid film
FIGUS, CRISTIANA;CASULA, MARIA FRANCESCA;
2009-01-01
Abstract
Organic-inorganic hybrid films containing layered organosilica, nanocrystals are obtained by an alcohol-free hydrolytic sol-gel process from a mono-functionalized organically modified alkoxide. Kinetically controlled self-organization is used to design the hybrid nanocomposite films. The layered nanocrystals are shown to be oriented within the films, which exhibited optical anisotropy (delta n > 10(-3)); the hybrid nanocomposite material is shown to be suitable for microfabrication by soft lithography. RI Takahashi, Masahide/C-3326-2009; Innocenzi, Plinio/D-5301-2009
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