The oxidation of gold powder by a new safe and powerful oxidising reagent, the bis-diiodine adduct of N,N'-dimethylperhydrodiazepine-2,3-dithione (D), to produce [AuI2D]I-3 under ambient conditions is described.
A powerful new oxidation agent towards metallic gold powder: N,N’-dimethylperhydrodiazepine-2,3-dithione (D) bis(diiodine). Synthesis and X-ray structure of [AuDI2]I3
DEPLANO, PAOLA;MERCURI, MARIA LAURA;SERPE, ANGELA;
1998-01-01
Abstract
The oxidation of gold powder by a new safe and powerful oxidising reagent, the bis-diiodine adduct of N,N'-dimethylperhydrodiazepine-2,3-dithione (D), to produce [AuI2D]I-3 under ambient conditions is described.
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