The electrochemical oxidation of N-methylbenzothiazole-2(3H)-selone leads to tetrakis[N-methylbenzothiazole-2(3H-selone]selenium(2+) tetrafluoroborate showing an uncommon dication containing a non-cyclic square-planar Se-5 framework; both Mulliken and NBO population analyses explain the relatively long Se-Se bond lengths between the central and the peripheral selenium atoms.
Electrochemical synthesis of tetrakis[N-methylbenzothiazole-2(3H)-selone]selenium(2+) tetrafluoroborate: an uncommon dication containing the mixed-valence Se5 framework
DEPLANO, PAOLA;ISAIA, FRANCESCO;LIPPOLIS, VITO;MERCURI, MARIA LAURA
1996-01-01
Abstract
The electrochemical oxidation of N-methylbenzothiazole-2(3H)-selone leads to tetrakis[N-methylbenzothiazole-2(3H-selone]selenium(2+) tetrafluoroborate showing an uncommon dication containing a non-cyclic square-planar Se-5 framework; both Mulliken and NBO population analyses explain the relatively long Se-Se bond lengths between the central and the peripheral selenium atoms.
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