The synthesis of pyridine derivatives is reported starting from the new dienamino esters 2. Thermal cyclization of 2 afforded the ethyl 2-amino-3-pyridinecarboxylate derivatives 3; from the reaction of 2 in sodium ethoxide the 2-aminopyridines 3 and 4, and the 1,2-dihydro-2-oxopyridines 5 and 6 were obtained.
Synthesis of pyridines by heterocyclization of new dienamino esters.
CONGIU, CENZO;
1990-01-01
Abstract
The synthesis of pyridine derivatives is reported starting from the new dienamino esters 2. Thermal cyclization of 2 afforded the ethyl 2-amino-3-pyridinecarboxylate derivatives 3; from the reaction of 2 in sodium ethoxide the 2-aminopyridines 3 and 4, and the 1,2-dihydro-2-oxopyridines 5 and 6 were obtained.File in questo prodotto:
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