The reaction of rhodanine vinyl bithiophene (BTR) with molecular dibromine (Br2) resulted in the formation of compound 1. Single-crystal X-ray diffraction analysis revealed bromination of the terminal thiophenyl ring and the formation of a 1:1 CT “spoke” adduct between the rhodanine thiocarbonyl group and a neutral dibromine (Br2) molecule.
5-((3′,5′-Dibromo-[2,2′-bithiophen]-5-yl)methyl)-3-ethyl-2-thioxothiazolidin-4-one∙Br2 (1:1)
Aragoni, Maria CarlaData Curation
;Lippolis, VitoInvestigation
;Pintus, AnnaData Curation
;Arca, MassimilianoConceptualization
;Sforazzini, Giuseppe
Conceptualization
2025-01-01
Abstract
The reaction of rhodanine vinyl bithiophene (BTR) with molecular dibromine (Br2) resulted in the formation of compound 1. Single-crystal X-ray diffraction analysis revealed bromination of the terminal thiophenyl ring and the formation of a 1:1 CT “spoke” adduct between the rhodanine thiocarbonyl group and a neutral dibromine (Br2) molecule.
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